Guides
Chem/Phys4C: Electrochemistry and electrical circuits and their elements

Magnetism

Magnetism governs some of the most clinically relevant physics on the MCAT — the mass spectrometer, MRI, and the deflection of charged particles all trace back to a single force law. Build the intuition first, then let the math follow.

Priority labels: Must know = cold; Know the logic = mechanism not names; Passage-level = recognize, don't memorize; Optional = skippable.


The Magnetic Field B

What Is a Magnetic Field?

Must know

A moving charge (or current) creates a magnetic field B\vec{B} that exerts a force on other moving charges. The key word is moving: a stationary charge feels no magnetic force and creates no magnetic field.

Field Lines and Direction

Must know

Magnetic field lines form closed loops — they never begin or end on a source (no magnetic monopoles). Outside a bar magnet they run from north to south pole; inside, from south to north. Around a straight current-carrying wire they are concentric circles.

Right-hand rule for a straight wire: point your right thumb in the direction of conventional current; your curling fingers show the direction of the circular B\vec{B} field lines.

Units and Magnitude

Must know

The SI unit is the Tesla (T). A smaller unit is the Gauss (G), where 1 T=104 G1\ \text{T} = 10^4\ \text{G}. Passage-level Earth's field is roughly 0.5 G0.5\ \text{G} (5×105 T5 \times 10^{-5}\ \text{T}); clinical MRI runs at 1.51.53 T3\ \text{T}.

Common Sources of Magnetic Fields

Know the logic

Recognize these, but the MCAT tests proportionality, not derivation.

SourceField MagnitudeNotes
Long straight wireB=μ0I2πrB = \dfrac{\mu_0 I}{2\pi r}rr = distance from wire
Solenoid (inside)B=μ0nIB = \mu_0 n Inn = turns per unit length

Here μ0=4π×107 T⋅m/A\mu_0 = 4\pi \times 10^{-7}\ \text{T·m/A} is the permeability of free space. Conceptual takeaway: doubling the current doubles the field; doubling the distance from a wire halves the field.


Quick check: A straight wire carries a current directed into the page. At a point directly above the wire, what is the direction of B\vec{B}?

Answer: By the right-hand rule, thumb into the page means the fingers curl clockwise as seen by the reader. Directly above the wire, the clockwise tangent points to the right. So B\vec{B} points to the right.


Magnetic Properties of Materials

Know the logic

The deciding factor is unpaired electrons. Distinguish the three types (MRI passages expect this); don't memorize the example lists.

TypeBehavior in a field
DiamagneticWeakly repelled; all electrons paired, induced moment opposes the field; effect vanishes when field is removed (e.g. water, Cu).
ParamagneticWeakly attracted; unpaired electrons partially align; no permanent magnetization (e.g. OX2\ce{O2}, transition-metal ions).
FerromagneticStrongly attracted; domains align and the material retains magnetization (Fe, Co, Ni).

This connects to electron configuration — molecular OX2\ce{O2} has two unpaired electrons, so it is paramagnetic.


The Lorentz Force

The Core Force Law

Must know

A particle with charge qq moving with velocity v\vec{v} through a magnetic field B\vec{B} feels the Lorentz force:

F=qv×B\vec{F} = q\vec{v} \times \vec{B}

with magnitude

F=qvBsinθ\boxed{F = qvB\sin\theta}

where θ\theta is the angle between v\vec{v} and B\vec{B}. Three consequences:

  1. Stationary (v=0v = 0): F=0F = 0.
  2. Parallel/antiparallel (θ=0°\theta = 0° or 180°180°): sinθ=0\sin\theta = 0, so F=0F = 0, no deflection.
  3. Maximum force at vB\vec{v} \perp \vec{B} (θ=90°\theta = 90°): F=qvBF = qvB.

The Right-Hand Rule for Force Direction

Must know

For v×B\vec{v} \times \vec{B}: point right-hand fingers along v\vec{v}, curl toward B\vec{B}, and your thumb gives the force direction for a positive charge. For a negative charge, flip the result. Practice until automatic — RHR appears in 2D and 3D (\odot = out of page, \otimes = into page) versions.

The Full Lorentz Force (Electric + Magnetic)

Must know

With both fields present:

F=q(E+v×B)\vec{F} = q(\vec{E} + \vec{v} \times \vec{B})

This is the basis of the velocity selector below.

Magnetic Force on a Current-Carrying Wire

Must know

Current is moving charge, so a straight wire of length LL at angle θ\theta to B\vec{B} feels:

F=BILsinθF = BIL\sin\theta

Direction: RHR with current in place of v\vec{v}. This is how MCAT passages test electric motors.

Force Between Two Parallel Wires

Know the logic

Each wire sits in the other's field. The frequently tested rule:

  • Parallel currents (same direction) attract.
  • Antiparallel currents repel.

(Opposite of the "like repels" intuition from electric charges.) Optional the force per unit length is F/L=μ0I1I2/2πdF/L = \mu_0 I_1 I_2 / 2\pi d, but the MCAT usually asks only for the direction.

Torque on a Current Loop (Motor Principle)

Know the logic

A current loop in a field feels no net force but a net torque that rotates it — the principle of the electric motor (a commutator reverses current each half-turn to keep rotation going one way). Recognizing this qualitatively is enough; you need not compute the loop's magnetic moment.


Quick check: An electron moves to the right in a region where B\vec{B} points out of the page. Which direction is the magnetic force on the electron?

Answer: By RHR, v\vec{v} (right) × B\times\ \vec{B} (out) points downward for a positive charge. The electron is negative, so the force is upward.


Motion of Charged Particles in Magnetic Fields

Why Magnetic Forces Curve (Not Speed Up) Particles

Must know

The magnetic force is always perpendicular to the velocity, so it does zero work (W=FdW = \vec{F} \cdot \vec{d}). Therefore:

  • Magnetic forces never change speed (kinetic energy).
  • They change only the direction of motion.

Circular Motion in a Uniform Magnetic Field

Must know

When vB\vec{v} \perp \vec{B} in a uniform field, the particle circles with the magnetic force as centripetal force:

qvB=mv2r    r=mvqBqvB = \frac{mv^2}{r} \implies \boxed{r = \frac{mv}{qB}}

This is high-yield. Larger mass or speed → larger radius; larger charge or stronger field → smaller (tighter) radius.

The period is

T=2πmqBT = \frac{2\pi m}{qB}

which is independent of speed — the operating principle of the cyclotron. The cyclotron frequency is f=1/T=qB/2πmf = 1/T = qB/2\pi m.

Helical Motion (Oblique Entry)

Passage-level

If a particle enters at an oblique angle, decompose its velocity — the component parallel to B\vec{B} is unaffected, the perpendicular component circles, giving helical (spiral) motion along the field lines (how charged particles spiral along Earth's field lines to produce the aurora).


Worked Example: Proton Deflected in a Magnetic Field

Must know

A proton (m=1.67×1027 kgm = 1.67 \times 10^{-27}\ \text{kg}, q=1.6×1019 Cq = 1.6 \times 10^{-19}\ \text{C}) moves at v=2.0×106 m/sv = 2.0 \times 10^6\ \text{m/s} perpendicular to B=0.50 TB = 0.50\ \text{T}. Find the radius.

r=mvqB=(1.67×1027)(2.0×106)(1.6×1019)(0.50)=3.34×10218.0×10200.042 m4.2 cmr = \frac{mv}{qB} = \frac{(1.67 \times 10^{-27})(2.0 \times 10^6)}{(1.6 \times 10^{-19})(0.50)} = \frac{3.34 \times 10^{-21}}{8.0 \times 10^{-20}} \approx 0.042\ \text{m} \approx 4.2\ \text{cm}

A few centimeters is reasonable for a proton in a half-Tesla field.


Key Applications (High-Yield MCAT Devices)

The Velocity Selector

Must know

In crossed E\vec{E} and B\vec{B} fields, a charge passes undeflected only when the electric and magnetic forces balance:

qE=qvB    v=EBqE = qvB \implies \boxed{v = \frac{E}{B}}

Only particles with exactly this speed pass straight through — the inlet stage of a mass spectrometer.

The Mass Spectrometer

Must know

After velocity selection, ions enter a uniform B\vec{B} and curve in semicircles, landing on a detector at distance 2r2r. Since r=mv/qBr = mv/qB, measuring rr gives the mass-to-charge ratio m/qm/q.

Mass spectrometer: lighter ions curve to a smaller radius than heavier ions, separating on the detector at distance 2r.
Mass spectrometer: lighter ions curve to a smaller radius than heavier ions, separating on the detector at distance 2r.

Different isotopes have the same charge but different mass, so they curve to different radii and separate — how isotope ratios are measured (e.g. X13X2213C\ce{^{13}C}-labeling).

The Cyclotron

Know the logic

Two D-shaped electrodes ("dees") in a uniform field; an alternating electric field at the gap adds kinetic energy each pass, and particles spiral outward. Because T=2πm/qBT = 2\pi m/qB is independent of speed, the alternating frequency stays constant and in sync. Medical cyclotrons make short-lived PET isotopes (X18X2218F\ce{^{18}F}, X11X2211C\ce{^{11}C}).


Quick check: In a mass spectrometer, a singly charged ion of mass 2m2m and one of mass mm enter the same field with the same speed. What is the ratio of their orbital radii?

Answer: Since r=mv/qBr = mv/qB with the same vv, BB, qq, radius is proportional to mass: r2m/rm=2r_{2m}/r_m = 2. The heavier ion curves twice as widely.


Common Confusions & Tricks

1. Magnetic vs. electric force on a stationary charge. A stationary charge feels no magnetic force but does feel an electric force. If a passage describes a particle that isn't moving, the electric force is responsible.

2. RHR for negative charges — always flip at the end. Do the RHR as if positive, then reverse for electrons/anions. Forgetting to flip is the most common error.

3. Magnetic force does no work. It cannot change kinetic energy. If a particle speeds up, an electric field is responsible.

4. The sinθ\sin\theta factor. Parallel motion = zero force; perpendicular = maximum force.

5. Radius direction of dependence. From r=mv/qBr = mv/qB, a stronger field gives a smaller radius (stronger BB = more force = tighter bend).

6. "Into the page" (\otimes) vs. "Out of the page" (\odot). \otimes = into the page (arrow feathers), \odot = out of the page (arrow tip). Confusing these flips every force direction.

7. Cyclotron period is independent of speed. T=2πm/qBT = 2\pi m/qB has no vv — this is why a cyclotron works.

8. Mass spectrometer measures m/qm/q, not mm alone. For singly ionized atoms rmr \propto m, but for multiply charged ions compare m/qm/q.


Key Equations

EquationVariables & Use
F=qvBsinθF = qvB\sin\thetaMagnetic force magnitude; θ\theta = angle between v\vec{v} and B\vec{B}
F=q(E+v×B)\vec{F} = q(\vec{E} + \vec{v} \times \vec{B})Full Lorentz force; direction from RHR; flip for negative charges
F=BILsinθF = BIL\sin\thetaForce on current-carrying wire; II = current, LL = length in field
r=mvqBr = \dfrac{mv}{qB}Cyclotron/Larmor radius; circular path in uniform B\vec{B}
T=2πmqBT = \dfrac{2\pi m}{qB}Cyclotron period; independent of speed
f=qB2πmf = \dfrac{qB}{2\pi m}Cyclotron frequency; f=1/Tf = 1/T
v=EBv = \dfrac{E}{B}Velocity selector condition
B=μ0I2πrB = \dfrac{\mu_0 I}{2\pi r}Field at distance rr from a long straight wire
B=μ0nIB = \mu_0 n IField inside a solenoid; nn = turns per unit length, μ0=4π×107 T⋅m/A\mu_0 = 4\pi\times10^{-7}\ \text{T·m/A}

Practice questions

Discrete practice questions written for this guide. Try them with full answers and explanations — sign in to save your progress.

Question 1 of 80 correct
discreteChem/Phys

Which of the following statements about magnetic fields is correct?